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NEET CHEMISTRYMedium

The half-life of a certain enzyme catalysed reaction is 138 s, that follows 1st order kinetics. The time required for the concentration of the substance to fall from 1.28 mg L11.28 \text{ mg L}^{-1} to 0.04 mg L10.04 \text{ mg L}^{-1}, is:

A

276 s

B

414 s

C

552 s

D

690 s

Step-by-Step Solution

For a first-order reaction, the concentration of the reactant remaining after nn half-lives is given by the relation:

[R]=[R]02n[R] = \frac{[R]_0}{2^n}

Given: Initial concentration, [R]0=1.28 mg L1[R]_0 = 1.28 \text{ mg L}^{-1} Final concentration, [R]=0.04 mg L1[R] = 0.04 \text{ mg L}^{-1}

Substituting these values into the equation: 0.04=1.282n0.04 = \frac{1.28}{2^n} 2n=1.280.04=322^n = \frac{1.28}{0.04} = 32 2n=252^n = 2^5 Therefore, the number of half-lives, n=5n = 5.

The total time required (tt) is the product of the number of half-lives and the half-life period (t1/2t_{1/2}): t=n×t1/2t = n \times t_{1/2} t=5×138 s=690 st = 5 \times 138 \text{ s} = 690 \text{ s}

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