Analyze BF3: Boron has 3 valence electrons and forms 3 bonds. The molecule is Trigonal Planar and symmetrical. The bond dipoles cancel out (mu=0). Non-polar.
Analyze SiF4: Silicon has 4 valence electrons and forms 4 bonds. The molecule is Tetrahedral and symmetrical. The bond dipoles cancel out (mu=0). Non-polar.
Analyze XeF4: Xenon has 8 valence electrons. It forms 4 bonds and has 2 lone pairs. The geometry is Square Planar (lone pairs are at 180^\\circ). The symmetry causes bond dipoles to cancel (mu=0). Non-polar.
Analyze SF4: Sulfur has 6 valence electrons. It forms 4 bonds with Fluorine, leaving 1 lone pair. The electron geometry is trigonal bipyramidal, and the molecular shape is See-Saw (asymmetrical). The dipole moments do not cancel (muneq0). It is polar.
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