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NEET CHEMISTRYMedium

Which of the following is a polar molecule?

A

SF₄

B

SiF₄

C

XeF₄

D

BF₃

Step-by-Step Solution

  1. Analyze BF3BF_3: Boron has 3 valence electrons and forms 3 bonds. The molecule is Trigonal Planar and symmetrical. The bond dipoles cancel out (mu=0\\mu = 0). Non-polar.
  2. Analyze SiF4SiF_4: Silicon has 4 valence electrons and forms 4 bonds. The molecule is Tetrahedral and symmetrical. The bond dipoles cancel out (mu=0\\mu = 0). Non-polar.
  3. Analyze XeF4XeF_4: Xenon has 8 valence electrons. It forms 4 bonds and has 2 lone pairs. The geometry is Square Planar (lone pairs are at 180^\\circ). The symmetry causes bond dipoles to cancel (mu=0\\mu = 0). Non-polar.
  4. Analyze SF4SF_4: Sulfur has 6 valence electrons. It forms 4 bonds with Fluorine, leaving 1 lone pair. The electron geometry is trigonal bipyramidal, and the molecular shape is See-Saw (asymmetrical). The dipole moments do not cancel (muneq0\\mu \\neq 0). It is polar.
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