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NEET CHEMISTRYMedium

The electronic configurations of Eu (Atomic no. 63), Gd (Atomic no. 64) and Tb (Atomic no. 65) are:

A

[Xe] 4f⁶ 5d¹ 6s², [Xe] 4f⁷ 5d¹ 6s² and [Xe] 4f⁹ 6s²

B

[Xe] 4f⁶ 5d¹ 6s², [Xe] 4f⁷ 5d¹ 6s² and [Xe] 4f⁸ 5d¹ 6s²

C

[Xe] 4f⁷ 6s², [Xe] 4f⁷ 5d¹ 6s² and [Xe] 4f⁹ 6s²

D

[Xe] 4f⁷ 6s², [Xe] 4f⁸ 6s² and [Xe] 4f⁸ 5d¹ 6s²

Step-by-Step Solution

The electronic configurations follow the Aufbau principle with exceptions driven by the stability of half-filled (f7f^7) and fully-filled (f14f^{14}) subshells.

  1. Europium (Eu, Z=63): [Xe] 4f76s24f^7 6s^2. The 4f4f orbital is exactly half-filled, providing extra stability.
  2. Gadolinium (Gd, Z=64): [Xe] 4f75d16s24f^7 5d^1 6s^2. To maintain the stable half-filled 4f74f^7 configuration, the incoming electron enters the 5d5d orbital instead of pairing in the 4f4f orbital.
  3. Terbium (Tb, Z=65): [Xe] 4f96s24f^9 6s^2. The electron from the 5d5d orbital (seen in Gd) moves to the 4f4f orbital along with the new electron, resulting in 4f94f^9.
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