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NEET CHEMISTRYMedium

Work done during reversible isothermal expansion of one mole of hydrogen gas at 25°C from a pressure of 20 atmospheres to a pressure of 10 atmospheres is: (Given: R = 2.0 cal K–1 mol–1)

A

–413.14 calories

B

413.14 calories

C

100 calories

D

0 calorie

Step-by-Step Solution

The work done (ww) during the reversible isothermal expansion of an ideal gas is given by the formula: w=2.303nRTlog10(V2V1)w = -2.303 nRT \log_{10}\left(\frac{V_2}{V_1}\right) Since P1V1=P2V2P_1V_1 = P_2V_2 for an isothermal process, we can also write this as: w=2.303nRTlog10(P1P2)w = -2.303 nRT \log_{10}\left(\frac{P_1}{P_2}\right)

Given the values: Number of moles, n=1n = 1 mol Universal gas constant, R=2.0 cal K1mol1R = 2.0 \text{ cal K}^{-1} \text{mol}^{-1} Temperature, T=25C=25+273=298 KT = 25^\circ\text{C} = 25 + 273 = 298 \text{ K} Initial pressure, P1=20 atmP_1 = 20 \text{ atm} Final pressure, P2=10 atmP_2 = 10 \text{ atm}

Substituting these values into the formula: w=2.303×1×2.0×298×log10(2010)w = -2.303 \times 1 \times 2.0 \times 298 \times \log_{10}\left(\frac{20}{10}\right) w=2.303×596×log10(2)w = -2.303 \times 596 \times \log_{10}(2) w=2.303×596×0.3010w = -2.303 \times 596 \times 0.3010 w413.14 caloriesw \approx -413.14 \text{ calories}

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