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NEET CHEMISTRYMedium

The concentration of ZnCl2ZnCl_2 solution will change when it is placed in a container which is made of:

A

Al

B

Cu

C

Ag

D

None

Step-by-Step Solution

A metal can displace another metal from its salt solution if it is more reactive, which means it must have a lower standard reduction potential (higher oxidation potential). According to the electrochemical series, Aluminium (Al) is more reactive than Zinc (Zn) because the standard reduction potential of Al (EAl3+/Al=1.66 VE^{\circ}_{Al^{3+}/Al} = -1.66\text{ V}) is lower than that of Zn (EZn2+/Zn=0.76 VE^{\circ}_{Zn^{2+}/Zn} = -0.76\text{ V}) . Therefore, an Aluminium container will react spontaneously with the ZnCl2ZnCl_2 solution (2Al+3Zn2+2Al3++3Zn2Al + 3Zn^{2+} \rightarrow 2Al^{3+} + 3Zn), causing the concentration of the solution to change. On the other hand, Copper (ECu2+/Cu=+0.34 VE^{\circ}_{Cu^{2+}/Cu} = +0.34\text{ V}) and Silver (EAg+/Ag=+0.80 VE^{\circ}_{Ag^{+}/Ag} = +0.80\text{ V}) have higher reduction potentials and are less reactive than zinc, so they will not react with the ZnCl2ZnCl_2 solution .

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