If enthalpies of formation of , and at and 1 atm pressure be 52, –394 and –286 kJ mol⁻¹ respectively, the enthalpy of combustion of will be [CBSE PMT 1995; AIIMS 1998; Pb. PMT 1999]:
+1412 kJ mol⁻¹
–1412 kJ mol⁻¹
+141.2 kJ mol⁻¹
–141.2 kJ mol⁻¹
The enthalpy of combustion () is calculated using the standard molar enthalpies of formation () of the products and reactants . First, we write the balanced thermochemical equation for the complete combustion of ethene (): .
According to thermodynamics, the reaction enthalpy is the sum of the enthalpies of the products minus the sum of the enthalpies of the reactants: .
By convention, the standard enthalpy of formation for an element in its reference state, such as , is taken as zero .
Substituting the values provided in the problem: .
The negative sign confirms that combustion is an exothermic process . This result matches Option B.
Join thousands of students and practice with AI-generated mock tests.