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NEET CHEMISTRYMedium

Given the following two reactions: A+BC+DA + B \rightleftharpoons C + D, with equilibrium constant K1K_1 E+FG+HE + F \rightleftharpoons G + H, with equilibrium constant K2K_2 What is the equilibrium constant for the reaction C+D+E+FA+B+G+HC + D + E + F \rightleftharpoons A + B + G + H?

A

K1/K2K_1/K_2

B

K2/K1K_2/K_1

C

K1K2K_1K_2

D

None of the above

Step-by-Step Solution

Let the given reactions be: (i) A+BC+DA + B \rightleftharpoons C + D; Equilibrium constant = K1K_1 (ii) E+FG+HE + F \rightleftharpoons G + H; Equilibrium constant = K2K_2

Reversing reaction (i), we get: (iii) C+DA+BC + D \rightleftharpoons A + B; Equilibrium constant = 1/K11/K_1 .

Now, add reaction (ii) and reaction (iii): (E+F)+(C+D)(G+H)+(A+B)(E + F) + (C + D) \rightleftharpoons (G + H) + (A + B) C+D+E+FA+B+G+HC + D + E + F \rightleftharpoons A + B + G + H

The equilibrium constant for a net reaction obtained by adding two reactions is the product of the equilibrium constants of the individual reactions . Therefore, the equilibrium constant for the new reaction is: K=(1K1)×K2=K2K1K = \left(\frac{1}{K_1}\right) \times K_2 = \frac{K_2}{K_1}.

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