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NEET CHEMISTRYMedium

The value of equilibrium constant of the reaction HI(g)12H2(g)+12I2(g)HI(g) \rightleftharpoons \frac{1}{2} H_2(g) + \frac{1}{2} I_2(g) is 8.08.0. The equilibrium constant of the reaction H2(g)+I2(g)2HI(g)H_2(g) + I_2(g) \rightleftharpoons 2HI(g) will be:

A

116\frac{1}{16}

B

164\frac{1}{64}

C

1616

D

18\frac{1}{8}

Step-by-Step Solution

Given reaction: HI(g)12H2(g)+12I2(g)HI(g) \rightleftharpoons \frac{1}{2} H_2(g) + \frac{1}{2} I_2(g); K1=8.0K_1 = 8.0

If we reverse the reaction, the equilibrium constant becomes the reciprocal of the original: 12H2(g)+12I2(g)HI(g)\frac{1}{2} H_2(g) + \frac{1}{2} I_2(g) \rightleftharpoons HI(g); K=1K1=18.0K' = \frac{1}{K_1} = \frac{1}{8.0}

Now, if we multiply this reaction by 22, the equilibrium constant is squared: H2(g)+I2(g)2HI(g)H_2(g) + I_2(g) \rightleftharpoons 2HI(g); K2=(K)2=(18.0)2=164K_2 = (K')^2 = \left(\frac{1}{8.0}\right)^2 = \frac{1}{64}

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