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NEET CHEMISTRYMedium

In a closed insulated container a liquid is stirred with a paddle to increase the temperature. The correct option regarding this among the following is:

A

∆E = W ≠ 0, q = 0

B

∆E = W = q ≠ 0

C

∆E = 0, W = q ≠ 0

D

W = 0, ∆E = q ≠ 0

Step-by-Step Solution

In a closed insulated container, there is no exchange of heat between the system and the surroundings. This makes it an adiabatic process, so q=0q = 0. Stirring the liquid with a paddle means mechanical work is done on the system, which raises its temperature, so W0W \neq 0. According to the first law of thermodynamics, the change in internal energy is given by ΔE=q+W\Delta E = q + W. Since q=0q = 0, the change in internal energy ΔE\Delta E is exactly equal to the work done on the system. Therefore, ΔE=W0\Delta E = W \neq 0.

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