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NEET CHEMISTRYMedium

Chloropicrin is obtained by the reaction of:

A

Nitric acid on chlorobenzene

B

Chlorine on picric acid

C

Nitric acid on chloroform

D

Steam on carbon tetrachloride

Step-by-Step Solution

Chloropicrin (CCl3NO2\text{CCl}_3\text{NO}_2), also known as nitrochloroform or tear gas, is obtained when chloroform (CHCl3\text{CHCl}_3) reacts with concentrated nitric acid (HNO3\text{HNO}_3). In this reaction, the hydrogen atom of chloroform is replaced by the nitro group (NO2-\text{NO}_2) from nitric acid. The chemical equation is: CHCl3+HNO3ΔCCl3NO2+H2O\text{CHCl}_3 + \text{HNO}_3 \xrightarrow{\Delta} \text{CCl}_3\text{NO}_2 + \text{H}_2\text{O}

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