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NEET CHEMISTRYMedium

Consider the given reaction: CH3COCH3dil. Ba(OH)2XCH_3COCH_3 \xrightarrow{\text{dil. } Ba(OH)_2} X The functional groups present in the compound "X" are:

A

Ketone and double bond

B

Double bond and aldehyde

C

Alcohol and aldehyde

D

Alcohol and ketone

Step-by-Step Solution

Acetone (CH3COCH3CH_3COCH_3) is a ketone that contains α\alpha-hydrogen atoms. When treated with a dilute alkali such as Ba(OH)2Ba(OH)_2, it undergoes an aldol condensation reaction. Two molecules of acetone undergo self-condensation to form a β\beta-hydroxy ketone (a ketol) as the initial product 'X' before heating. The structure of 'X' is CH3C(OH)(CH3)CH2COCH3CH_3-C(OH)(CH_3)-CH_2-CO-CH_3 (4-hydroxy-4-methylpentan-2-one). Thus, the functional groups present in compound 'X' are an alcohol (OH-OH) and a ketone (>C=O>C=O).

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