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NEET CHEMISTRYEasy

The activation energy of a reaction can be determined from the slope of the graph between:

A

lnk\ln k vs TT

B

lnkT\frac{\ln k}{T} vs TT

C

lnk\ln k vs 1T\frac{1}{T}

D

Tlnk\frac{T}{\ln k} vs 1T\frac{1}{T}

Step-by-Step Solution

According to the Arrhenius equation, k=AeEa/RTk = A e^{-E_a/RT}. Taking the natural logarithm on both sides, we get lnk=lnAEaRT\ln k = \ln A - \frac{E_a}{RT}. This equation is of the form y=mx+cy = mx + c, representing a straight line where y=lnky = \ln k, x=1Tx = \frac{1}{T}, slope m=EaRm = -\frac{E_a}{R}, and intercept c=lnAc = \ln A. Therefore, a plot of lnk\ln k versus 1T\frac{1}{T} gives a straight line. By determining its slope, the activation energy (EaE_a) can be calculated.

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