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NEET CHEMISTRYEasy

Consider the given reaction: PCl5PCl3+Cl2\text{PCl}_5 \rightleftharpoons \text{PCl}_3 + \text{Cl}_2. At equilibrium at 500 K500\text{ K}, the concentration of PCl5=1.40 M\text{PCl}_5 = 1.40\text{ M}, concentration of Cl2=1.60 M\text{Cl}_2 = 1.60\text{ M}, concentration of PCl3=1.60 M\text{PCl}_3 = 1.60\text{ M}. Calculate KcK_c:

A

2

B

2.6

C

1.83

D

3.4

Step-by-Step Solution

For the given reaction: PCl5PCl3+Cl2\text{PCl}_5 \rightleftharpoons \text{PCl}_3 + \text{Cl}_2

The expression for the equilibrium constant KcK_c is: Kc=[PCl3][Cl2][PCl5]K_c = \frac{[\text{PCl}_3][\text{Cl}_2]}{[\text{PCl}_5]}

Given equilibrium concentrations: [PCl5]=1.40 M[\text{PCl}_5] = 1.40\text{ M} [Cl2]=1.60 M[\text{Cl}_2] = 1.60\text{ M} [PCl3]=1.60 M[\text{PCl}_3] = 1.60\text{ M}

Substituting these values into the equilibrium expression: Kc=1.60×1.601.40K_c = \frac{1.60 \times 1.60}{1.40} Kc=2.561.401.83K_c = \frac{2.56}{1.40} \approx 1.83

Therefore, the value of KcK_c is 1.831.83.

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