In a reaction, , the rate is doubled when the concentration of is doubled, and the rate increases by a factor of when the concentrations of both the reactants ( and ) are doubled. The rate law for the reaction can be written as:
Let the rate law be expressed as:
According to the first condition, when the concentration of is doubled, the rate is doubled: Dividing this by the initial rate equation gives:
According to the second condition, when the concentrations of both and are doubled, the rate increases by a factor of 8: Dividing this by the initial rate equation gives: Substituting the value of :
Therefore, the overall rate law for the reaction is .
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