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NEET CHEMISTRYMedium

In a reaction, A+BProductA + B \rightarrow \text{Product}, the rate is doubled when the concentration of BB is doubled, and the rate increases by a factor of 88 when the concentrations of both the reactants (AA and BB) are doubled. The rate law for the reaction can be written as:

A

Rate=k[A][B]2\text{Rate} = k[A][B]^2

B

Rate=k[A]2[B]2\text{Rate} = k[A]^2[B]^2

C

Rate=k[A][B]\text{Rate} = k[A][B]

D

Rate=k[A]2[B]\text{Rate} = k[A]^2[B]

Step-by-Step Solution

Let the rate law be expressed as: Rate=k[A]x[B]y\text{Rate} = k[A]^x[B]^y

According to the first condition, when the concentration of BB is doubled, the rate is doubled: 2×Rate=k[A]x(2[B])y2 \times \text{Rate} = k[A]^x(2[B])^y Dividing this by the initial rate equation gives: 2=2y    y=12 = 2^y \implies y = 1

According to the second condition, when the concentrations of both AA and BB are doubled, the rate increases by a factor of 8: 8×Rate=k(2[A])x(2[B])y8 \times \text{Rate} = k(2[A])^x(2[B])^y Dividing this by the initial rate equation gives: 8=2x×2y8 = 2^x \times 2^y Substituting the value of y=1y = 1: 8=2x×21    2x=4    x=28 = 2^x \times 2^1 \implies 2^x = 4 \implies x = 2

Therefore, the overall rate law for the reaction is Rate=k[A]2[B]1=k[A]2[B]\text{Rate} = k[A]^2[B]^1 = k[A]^2[B].

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