The colour of transition metal ions is generally attributed to the presence of unpaired d-electrons, which undergo d−d transitions by absorbing light from the visible region.
- Cr3+ has the electronic configuration [Ar]3d3. Because it has 3 unpaired d-electrons, it undergoes d−d transitions and forms a coloured aqueous solution (typically violet or green).
- Cu+ has the electronic configuration [Ar]3d10. Since it has a completely filled d-orbital and no unpaired electrons, it is colourless.
- Na+ has a completely filled noble gas core configuration [Ne]. Having no unpaired electrons, it is also colourless.