The basic character of the transition metal monoxides follows the order: (Atomic nos. Ti = 22, V = 23, Cr = 24, Fe = 26)
VO > CrO > TiO > FeO
CrO > VO > FeO > TiO
TiO > FeO > VO > CrO
TiO > VO > CrO > FeO
All the given transition metals are in the +2 oxidation state (monoxides). For transition metal oxides in the same oxidation state, the basic character generally decreases from left to right across a period. This is because the atomic size decreases and the effective nuclear charge increases, leading to an increase in the ionization enthalpy and a decrease in the metallic character. Consequently, the covalent character of the metal-oxygen bond increases, which reduces the basic nature of the oxide. Since the atomic numbers are in the order Ti (22) < V (23) < Cr (24) < Fe (26), the basic character decreases in the same order: TiO > VO > CrO > FeO.
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