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NEET CHEMISTRYMedium

In the silver plating of copper, K[Ag(CN)2]K[Ag(CN)_2] is used instead of AgNO3AgNO_3. The reason is:

A

A thin layer of Ag is formed on Cu

B

More voltage is required

C

Ag+Ag^+ ions are completely removed from the solution

D

Less availability of Ag+Ag^+ ions, as Cu can not displace Ag from [Ag(CN)2][Ag(CN)_2]^- ion

Step-by-Step Solution

Copper is more reactive than silver (ECu2+/Cu=+0.34 VE^{\circ}_{Cu^{2+}/Cu} = +0.34\text{ V} and EAg+/Ag=+0.80 VE^{\circ}_{Ag^+/Ag} = +0.80\text{ V}). If a simple salt like AgNO3AgNO_3 is used, Cu will spontaneously displace Ag from the solution via the redox reaction Cu+2Ag+Cu2++2AgCu + 2Ag^+ \rightarrow Cu^{2+} + 2Ag, leading to a loose and non-adherent deposit of silver. To get a smooth, uniform, and adherent coating of silver by electrolysis, the concentration of free Ag+Ag^+ ions must be kept very low. K[Ag(CN)2]K[Ag(CN)_2] is a highly stable complex salt that dissociates very little, providing a very low concentration of free Ag+Ag^+ ions. At this low concentration, copper cannot displace silver chemically, and deposition occurs only when an external electric current is passed.

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