Let the given equations be:
(i) 21A→B;ΔH1=+150 kJ/mol
Multiplying equation (i) by 2, we get:
A→2B;ΔH4=+300 kJ/mol ... (iv)
(ii) 3B→2C+D;ΔH2=−125 kJ/mol
(iii) E+A→2D;ΔH3=+350 kJ/mol
Reversing equation (iii), we get:
2D→E+A;ΔH5=−350 kJ/mol ... (v)
Now, adding equations (iv), (ii), and (v):
(A)+(3B)+(2D)→(2B)+(2C+D)+(E+A)
⇒B+D→E+2C
According to Hess's Law, the total enthalpy change for the reaction will be the sum of the enthalpy changes of these steps:
ΔH=ΔH4+ΔH2+ΔH5
ΔH=(+300)+(−125)+(−350)=−175 kJ/mol