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NEET CHEMISTRYEasy

Among the following, the compound that is electron deficient is:

A

BaCl2BaCl_{2}

B

BCl3BCl_{3}

C

CCl4CCl_{4}

D

PCl5PCl_{5}

Step-by-Step Solution

According to the octet rule, atoms generally form bonds to achieve a stable configuration of eight electrons in their valence shell . However, there are several exceptions to this rule . One such exception is the incomplete octet of the central atom, which is characteristic of electron-deficient compounds . In BCl3BCl_{3}, the central boron atom has three valence electrons and forms three covalent bonds with chlorine atoms. This results in a total of only six electrons surrounding the boron atom . Since this is fewer than the eight electrons required for an octet, BCl3BCl_{3} is electron deficient. In contrast, CCl4CCl_{4} follows the octet rule with eight electrons, and PCl5PCl_{5} represents an 'expanded octet' with ten electrons .

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