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NEET CHEMISTRYMedium

When copper is heated with conc. HNO3\text{HNO}_3 it produces:

A

Cu(NO3)\text{Cu}(\text{NO}_3) and NO\text{NO}

B

Cu(NO3)2\text{Cu}(\text{NO}_3)_2, NO\text{NO} and NO2\text{NO}_2

C

Cu(NO3)2\text{Cu}(\text{NO}_3)_2 and N2O\text{N}_2\text{O}

D

Cu(NO3)2\text{Cu}(\text{NO}_3)_2 and NO2\text{NO}_2

Step-by-Step Solution

When copper is heated with concentrated nitric acid (HNO3\text{HNO}_3), it undergoes oxidation to form copper(II) nitrate, while the nitric acid acts as an oxidizing agent and is reduced to nitrogen dioxide (NO2\text{NO}_2) gas. The balanced chemical equation for the reaction is: Cu+4HNO3 (conc.)Cu(NO3)2+2NO2+2H2O\text{Cu} + 4\text{HNO}_3 \text{ (conc.)} \rightarrow \text{Cu}(\text{NO}_3)_2 + 2\text{NO}_2 \uparrow + 2\text{H}_2\text{O} Note: If dilute HNO3\text{HNO}_3 is used, it produces nitric oxide (NO\text{NO}) instead of NO2\text{NO}_2.

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