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NEET CHEMISTRYMedium

Identify the correct reagents that would bring about the following transformation (Alkene \rightarrow Alcohol):

A

(i) BH3BH_3

B

(i) BH3BH_3 (ii) H2O2/OHH_2O_2/OH^-

C

(i) PCC (ii) alk. KMnO4KMnO_4

D

(i) H2O/H+H_2O/H^+ (ii) PCC

Step-by-Step Solution

The transformation of an alkene to an alcohol can be achieved via Hydroboration-Oxidation.

  1. Step 1: The alkene reacts with diborane (B2H6B_2H_6 or BH3BH_3) to form a trialkylborane. This is an electrophilic addition reaction.
  2. Step 2: The trialkylborane is oxidised by alkaline hydrogen peroxide (H2O2/OHH_2O_2/OH^-) to form an alcohol.

This reaction is characterized by the Anti-Markovnikov addition of water (the -OH group attaches to the less substituted carbon atom) and syn-addition (H and OH add to the same side). Reagents like H2O/H+H_2O/H^+ (Acid catalysed hydration) would follow Markovnikov's rule.

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