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NEET CHEMISTRYEasy

An example of a sigma bonded organometallic compound is:

A

Grignard's reagent

B

Ferrocene

C

Cobaltocene

D

Ruthenocene

Step-by-Step Solution

Organometallic compounds are classified based on the nature of the metal-carbon bond:

  1. Sigma (σ\sigma ) bonded organometallics: In these compounds, the metal atom and carbon atom are joined by a single covalent bond (sigma bond). Grignard's reagents (RMgXR-Mg-X) are a classic example where the alkyl group is bonded to the magnesium atom via a sigma bond . Other examples include (CH3)4Sn(CH_3)_4Sn, (C2H5)2Zn(C_2H_5)_2Zn, etc.
  2. Pi (π\pi ) bonded organometallics: These involve transition metals bonded to unsaturated ligands via their π\pi -electron clouds. Ferrocene [Fe(η5C5H5)2][Fe(\eta^5-C_5H_5)_2], Cobaltocene [Co(η5C5H5)2][Co(\eta^5-C_5H_5)_2], and Ruthenocene [Ru(η5C5H5)2][Ru(\eta^5-C_5H_5)_2] are all metallocenes (sandwich compounds) where the metal is π\pi -bonded to two cyclopentadienyl rings.

Therefore, Grignard's reagent is the correct example of a sigma bonded organometallic compound.

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