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NEET CHEMISTRYMedium

4d, 5p, 5f and 6p orbitals are arranged in the order of decreasing energy. The correct option is

1

5f>6p>5p>4d5f > 6p > 5p > 4d

2

6p>5f>5p>4d6p > 5f > 5p > 4d

3

6p>5f>4d>5p6p > 5f > 4d > 5p

4

5f>6p>4d>5p5f > 6p > 4d > 5p

Step-by-Step Solution

Using the (n+l)(n + l) rule: For 4d, n=4,l=2,n+l=6n=4, l=2, n+l=6. For 5p, n=5,l=1,n+l=6n=5, l=1, n+l=6. For 5f, n=5,l=3,n+l=8n=5, l=3, n+l=8. For 6p, n=6,l=1,n+l=7n=6, l=1, n+l=7. Comparing (n+l)(n+l) values: 5f(8)>6p(7)>4d(6)=5p(6)5f(8) > 6p(7) > 4d(6) = 5p(6). Since 4d and 5p have the same (n+l)(n+l), the one with higher nn has higher energy, so 5p>4d5p > 4d. Thus, the order is 5f>6p>5p>4d5f > 6p > 5p > 4d.

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