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NEET CHEMISTRYEasy

Ethylbenzene is obtained from phenyl methyl ketone by using:

A

Zn–Hg+HCl

B

LiAlH4

C

KMnO4

D

None of the above

Step-by-Step Solution

Phenyl methyl ketone is Acetophenone (C6H5COCH3C_6H_5COCH_3). The conversion of acetophenone to ethylbenzene (C6H5CH2CH3C_6H_5CH_2CH_3) involves the reduction of the carbonyl group (>C=O>C=O) to a methylene group (CH2-CH_2-). This specific transformation is achieved using Zinc amalgam and concentrated hydrochloric acid (Zn-Hg + HCl), a reaction known as the Clemmensen Reduction.

LiAlH4LiAlH_4 is a reducing agent that would reduce the ketone to a secondary alcohol (1-phenylethanol), not a hydrocarbon. KMnO4KMnO_4 is a strong oxidizing agent and would not reduce the carbonyl group.

  • Zn-Hg/HCl is the standard reagent for reducing aldehydes and ketones to alkanes in acidic media.
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