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NEET CHEMISTRYMedium

The rate of a first-order reaction is 0.04 mol L1 s10.04 \text{ mol L}^{-1} \text{ s}^{-1} at 10 sec10 \text{ sec} and 0.03 mol L1 s10.03 \text{ mol L}^{-1} \text{ s}^{-1} at 20 sec20 \text{ sec} after initiation of the reaction. The half-life period of the reaction is

A

34.1 s34.1 \text{ s}

B

44.1 s44.1 \text{ s}

C

54.1 s54.1 \text{ s}

D

24.7 s24.7 \text{ s}

Step-by-Step Solution

For a first-order reaction, the rate is directly proportional to the concentration of the reactant: Rate=k[A]\text{Rate} = k[A]. Therefore, the ratio of rates at two different times is equal to the ratio of concentrations at those times: Rate1Rate2=[A]1[A]2=0.040.03=43\frac{\text{Rate}_1}{\text{Rate}_2} = \frac{[A]_1}{[A]_2} = \frac{0.04}{0.03} = \frac{4}{3}

The rate constant kk can be calculated using the integrated rate equation between time t1t_1 and t2t_2: k=2.303t2t1log[A]1[A]2k = \frac{2.303}{t_2 - t_1} \log \frac{[A]_1}{[A]_2} k=2.3032010log(43)=2.30310(log4log3)k = \frac{2.303}{20 - 10} \log \left(\frac{4}{3}\right) = \frac{2.303}{10} (\log 4 - \log 3) k=2.30310(0.60210.4771)=0.2303×0.12500.0287 s1k = \frac{2.303}{10} (0.6021 - 0.4771) = 0.2303 \times 0.1250 \approx 0.0287 \text{ s}^{-1}

The half-life period (t1/2t_{1/2}) is given by: t1/2=0.693k=0.6930.028724.14 st_{1/2} = \frac{0.693}{k} = \frac{0.693}{0.0287} \approx 24.14 \text{ s}.

Note: The exact calculation yields approximately 24.1 s24.1 \text{ s} (which was the intended option in the actual NEET exam), making 24.7 s24.7 \text{ s} the closest available choice or a likely typographical error in the provided options.

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