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NEET CHEMISTRYEasy

When a liquid boils, there is [JIPMER 2002]:

A

An increase in entropy

B

A decrease in entropy

C

An increase in heat of vaporization

D

An increase in free energy

Step-by-Step Solution

Boiling is the phase transformation of a substance from a liquid to a gas . Thermodynamics defines entropy (SS) as a measure of the degree of randomness or disorder within a system . Among the states of matter, the gaseous state is the state of highest entropy because of the increased chaotic motion of particles compared to the liquid state . Consequently, the transition from liquid to vapour during boiling is accompanied by a significant increase in entropy . Furthermore, at the boiling point, the liquid and gas phases are in dynamic equilibrium, where the change in Gibbs free energy is zero (ΔG=0\Delta G = 0), making an increase in free energy incorrect .

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