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NEET CHEMISTRYMedium

When electromagnetic radiation of wavelength 300 nm300 \text{ nm} falls on the surface of a metal, electrons are emitted with the kinetic energy of 1.68×105 J mol11.68 \times 10^5 \text{ J mol}^{-1}. The minimum energy needed to remove one mole of electron from the metal is: (Given: h=6.626×1034 J sh = 6.626 \times 10^{-34} \text{ J s}, c=3×108 m s1c = 3 \times 10^8 \text{ m s}^{-1}, NA=6.022×1023 mol1N_A = 6.022 \times 10^{23} \text{ mol}^{-1})

A

2.31 × 10⁶ J mol⁻¹

B

3.84 × 10⁴ J mol⁻¹

C

3.84 × 10⁻¹⁹ J mol⁻¹

D

2.31 × 10⁵ J mol⁻¹

Step-by-Step Solution

  1. Calculate the energy of one mole of photons (EE): The energy of a photon is given by E=hcλE = \frac{hc}{\lambda}. For one mole, we multiply by Avogadro's constant (NAN_A). E=NAhcλE = \frac{N_A hc}{\lambda} Given: NA=6.022×1023 mol1N_A = 6.022 \times 10^{23} \text{ mol}^{-1} h=6.626×1034 J sh = 6.626 \times 10^{-34} \text{ J s} c=3.0×108 m s1c = 3.0 \times 10^8 \text{ m s}^{-1} λ=300 nm=300×109 m=3.0×107 m\lambda = 300 \text{ nm} = 300 \times 10^{-9} \text{ m} = 3.0 \times 10^{-7} \text{ m}

E=(6.022×1023 mol1)(6.626×1034 J s)(3.0×108 m s1)3.0×107 mE = \frac{(6.022 \times 10^{23} \text{ mol}^{-1})(6.626 \times 10^{-34} \text{ J s})(3.0 \times 10^8 \text{ m s}^{-1})}{3.0 \times 10^{-7} \text{ m}} E=11.969×1033.0×107 J mol13.99×105 J mol1E = \frac{11.969 \times 10^{-3}}{3.0 \times 10^{-7}} \text{ J mol}^{-1} \approx 3.99 \times 10^5 \text{ J mol}^{-1}

  1. Apply the Photoelectric Equation: Energy of photon = Minimum energy to remove electron (Work Function) + Kinetic Energy E=W0+K.E.E = W_0 + K.E. W0=EK.E.W_0 = E - K.E.

  2. Calculate the Work Function (W0W_0): Given K.E.=1.68×105 J mol1K.E. = 1.68 \times 10^5 \text{ J mol}^{-1} W0=(3.99×105 J mol1)(1.68×105 J mol1)W_0 = (3.99 \times 10^5 \text{ J mol}^{-1}) - (1.68 \times 10^5 \text{ J mol}^{-1}) W0=(3.991.68)×105 J mol1W_0 = (3.99 - 1.68) \times 10^5 \text{ J mol}^{-1} W0=2.31×105 J mol1W_0 = 2.31 \times 10^5 \text{ J mol}^{-1}

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