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NEET CHEMISTRYMedium

The correct order of ionic radii of Y3+Y^{3+}, La3+La^{3+}, Eu3+Eu^{3+}, and Lu3+Lu^{3+} is: (Atomic nos. Y = 39, La = 57, Eu = 63, Lu = 71)

A

Y3+<La3+<Eu3+<Lu3+Y^{3+} < La^{3+} < Eu^{3+} < Lu^{3+}

B

Y3+<Lu3+<Eu3+<La3+Y^{3+} < Lu^{3+} < Eu^{3+} < La^{3+}

C

Lu3+<Eu3+<La3+<Y3+Lu^{3+} < Eu^{3+} < La^{3+} < Y^{3+}

D

La3+<Eu3+<Lu3+<Y3+La^{3+} < Eu^{3+} < Lu^{3+} < Y^{3+}

Step-by-Step Solution

Due to the lanthanoid contraction, there is a steady decrease in the ionic radii of M3+M^{3+} ions as the atomic number increases from Lanthanum to Lutetium. Therefore, the order among the given lanthanoids is La3+>Eu3+>Lu3+La^{3+} > Eu^{3+} > Lu^{3+}. Yttrium (Y3+Y^{3+}) belongs to the 4d transition series (Period 5) and is placed just above Lanthanum in Group 3. Its ionic radius is significantly smaller than that of La3+La^{3+} and is comparable to the heavier lanthanoids (approx. 90 pm). Although strictly speaking Lu3+Lu^{3+} (86 pm) is slightly smaller than Y3+Y^{3+}, the most appropriate sequence among the given options that correctly places La3+La^{3+} as the largest and maintains the relative order for the lanthanoids is Y3+<Lu3+<Eu3+<La3+Y^{3+} < Lu^{3+} < Eu^{3+} < La^{3+}.

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