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NEET CHEMISTRYMedium

The correct acidic order of the following is: (I) [Structure Missing] (II) [Structure Missing] (III) [Structure Missing]

A

I > II > III

B

III > I > II

C

II > III > I

D

I > III > II

Step-by-Step Solution

The acidic strength of phenols is governed by the stability of the phenoxide ion formed after the loss of a proton.

  1. Electron-Withdrawing Groups (EWG): Substituents like NO2-NO_2, CN-CN, and halogens withdraw electrons from the benzene ring (via I-I and R-R effects). This delocalises the negative charge on the phenoxide oxygen, stabilizing the ion and increasing acidity , .
  2. Electron-Donating Groups (EDG): Substituents like alkyl groups (e.g., CH3-CH_3) or alkoxy groups release electrons (via +I+I or +R+R effects). This intensifies the negative charge on the phenoxide oxygen, destabilizing the ion and decreasing acidity.

Given the correct order III > I > II, it can be inferred that:

  • Compound (III) likely contains an electron-withdrawing group (making it the most acidic).
  • Compound (II) likely contains an electron-donating group (making it the least acidic).
  • Compound (I) is likely the unsubstituted phenol or has an intermediate substituent effect.
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