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NEET CHEMISTRYEasy

Ethyl benzoate can be prepared from benzoic acid by using:

A

Propyl alcohol

B

Ethyl alcohol and dry HCl

C

Ethyl chloride

D

Sodium ethoxide

Step-by-Step Solution

Ethyl benzoate (C6H5COOC2H5C_6H_5COOC_2H_5) is an ester formed by the reaction of benzoic acid (C6H5COOHC_6H_5COOH) with ethyl alcohol (C2H5OHC_2H_5OH). This reaction is a classic example of Fischer Esterification, which requires an acid catalyst to proceed.

The reaction is reversible and is catalyzed by acids like concentrated H2SO4H_2SO_4 or dry HCl gas. The acid protonates the carbonyl oxygen of the carboxylic acid, making it more susceptible to nucleophilic attack by the alcohol molecule. Dry HCl also helps in shifting the equilibrium to the right by absorbing the water produced (acting as a dehydrating agent).

C6H5COOH+C2H5OHdry HClC6H5COOC2H5+H2OC_6H_5COOH + C_2H_5OH \xrightarrow{\text{dry HCl}} C_6H_5COOC_2H_5 + H_2O

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