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NEET CHEMISTRYMedium

The manganate and permanganate ions are tetrahedral, due to :

1

The π\pi-bonding involves overlap of p-orbitals of oxygen with d-orbitals of manganese

2

There is no π\pi-bonding

3

The π\pi-bonding involves overlap of p-orbitals of oxygen with p-orbitals of manganese

4

The π\pi-bonding involves overlap of d-orbitals of oxygen with d-orbitals of manganese

Step-by-Step Solution

In MnO42MnO_4^{2-} and MnO4MnO_4^-, the tetrahedral geometry is stabilized by pπdπp\pi-d\pi bonding where oxygen's p-orbitals overlap with manganese's d-orbitals.

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