Match List-I with List-II:
List-I (Complexes) (A) and (B) and (C) and (D) and
List-II (Type of isomer) (I) Ionisation isomerism (II) Coordination isomerism (III) Linkage isomerism (IV) Solvate isomerism
Choose the correct answer from the options given below:
(A)-(III), (B)-(I), (C)-(II), (D)-(IV)
(A)-(II), (B)-(III), (C)-(IV), (D)-(I)
(A)-(III), (B)-(II), (C)-(I), (D)-(IV)
(A)-(IV), (B)-(III), (C)-(II), (D)-(I)
(A) Linkage isomerism arises in a coordination compound containing an ambidentate ligand. In and , the nitrite ligand binds either through nitrogen or oxygen. (A III) (B) Coordination isomerism arises from the interchange of ligands between cationic and anionic entities of different metal ions present in a complex. (B II) (C) Ionisation isomerism arises when the counter ion in a complex salt is itself a potential ligand and can displace a ligand which can then become the counter ion. Here, and interchange. (C I) (D) Solvate (hydrate) isomerism differs by whether or not a solvent (water) molecule is directly bonded to the metal ion or merely present as free solvent molecules in the crystal lattice. (D IV) Therefore, the correct match is (A)-(III), (B)-(II), (C)-(I), (D)-(IV).
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