Back to Directory
NEET CHEMISTRYMedium

The Gibb's energy for the decomposition of Al2O3Al_2O_3 at 500C500^{\circ}\text{C} is as follows: 23Al2O343Al+O2 ; ΔrG=+960 kJ mol1\frac{2}{3}Al_2O_3 \rightarrow \frac{4}{3}Al + O_2 \ ; \ \Delta_rG = + 960 \text{ kJ mol}^{-1} The potential difference needed for the electrolytic reduction of aluminium oxide (Al2O3Al_2O_3) at 500C500^{\circ}\text{C} is at least:

A

3.0 V

B

2.5 V

C

5.0 V

D

4.5 V

Step-by-Step Solution

The given reaction for the decomposition of Al2O3Al_2O_3 is: 23Al2O343Al+O2\frac{2}{3}Al_2O_3 \rightarrow \frac{4}{3}Al + O_2 In this reaction, 43\frac{4}{3} moles of Al3+Al^{3+} ions are reduced to Al atoms. The number of electrons involved (nn) can be calculated from either the reduction of Al or oxidation of O: For Al: n=43×3=4n = \frac{4}{3} \times 3 = 4 moles of electrons. For O: 2O2O2+4e2O^{2-} \rightarrow O_2 + 4e^-, so n=4n = 4. We know the relation between standard Gibbs energy and minimum external potential (EE) required for electrolysis: ΔrG=nFE\Delta_rG = nFE Given ΔrG=+960 kJ mol1=960×103 J mol1\Delta_rG = +960 \text{ kJ mol}^{-1} = 960 \times 10^3 \text{ J mol}^{-1} and F96500 C mol1F \approx 96500 \text{ C mol}^{-1}. 960×103=4×96500×E960 \times 10^3 = 4 \times 96500 \times E E=960×1034×96500=960000386000=2.487 V2.5 VE = \frac{960 \times 10^3}{4 \times 96500} = \frac{960000}{386000} = 2.487 \text{ V} \approx 2.5 \text{ V} Hence, the minimum potential difference needed for the electrolytic reduction is 2.5 V2.5 \text{ V}.

Practice Mode Available

Master this Topic on Sushrut

Join thousands of students and practice with AI-generated mock tests.

Get Started
Solved: CHEMISTRY Question for NEET | Sushrut