The Gibb's energy for the decomposition of at is as follows: The potential difference needed for the electrolytic reduction of aluminium oxide () at is at least:
3.0 V
2.5 V
5.0 V
4.5 V
The given reaction for the decomposition of is: In this reaction, moles of ions are reduced to Al atoms. The number of electrons involved () can be calculated from either the reduction of Al or oxidation of O: For Al: moles of electrons. For O: , so . We know the relation between standard Gibbs energy and minimum external potential () required for electrolysis: Given and . Hence, the minimum potential difference needed for the electrolytic reduction is .
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