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NEET CHEMISTRYMedium

Identify the pair of Lanthanoides with one strong oxidant and one strong reductant:

A

Ce(IV), Tb(IV)

B

Yb(II), Eu(II)

C

Eu(IV), Lu(III)

D

Ce(IV), Eu(II)

Step-by-Step Solution

In the lanthanoids, the most common and stable oxidation state is +3. Ions that exhibit +2 and +4 states tend to revert to the +3 state to achieve stability. The formation of CeIVCe^{IV} is favoured by its stable noble gas configuration, but it acts as a strong oxidant (oxidising agent) because it readily accepts an electron to revert to the common +3 state. Conversely, Eu2+Eu^{2+} is formed by losing its two s electrons, leaving a highly stable half-filled f7f^7 configuration. However, it acts as a strong reducing agent (reductant) as it loses an electron to change back to the common +3 state . Thus, the pair with one strong oxidant and one strong reductant is Ce(IV) and Eu(II).

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