A and B in the following reactions are: (i) (ii)
A = RCOOH, B = RCHO
A = RCHO, B = RCOOH
A = RCH_2OH, B = RCHO
A = RCHO, B = RCHO
Reaction (i): Rosenmund Reduction Acyl chlorides () are hydrogenated over a catalyst, palladium on barium sulphate (). This reaction is used exclusively for the preparation of aldehydes (). The catalyst is poisoned with sulphur or quinoline to prevent further reduction to primary alcohols.
Reaction (ii): Stephen Reaction Nitriles () are reduced to imines with stannous chloride in the presence of hydrochloric acid (), which on hydrolysis give the corresponding aldehyde ().
Thus, both products A and B are aldehydes ().
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