Let the given reactions be:
(i) Fe2O3(s)+3CO(g)→2Fe(s)+3CO2(g);ΔH1=−26.88 kJ
(ii) FeO(s)+CO(g)→Fe(s)+CO2(g);ΔH2=−16.5 kJ
The target reaction is:
Fe2O3(s)+CO(g)→2FeO(s)+CO2(g);ΔH=?
By applying Hess's Law, we can obtain the target reaction by reversing equation (ii), multiplying it by 2, and then adding it to equation (i):
Reverse equation (ii) and multiply by 2:
2Fe(s)+2CO2(g)→2FeO(s)+2CO(g);ΔH3=2×(+16.5 kJ)=+33.0 kJ
Now, add this to equation (i):
[Fe2O3(s)+3CO(g)]+[2Fe(s)+2CO2(g)]→[2Fe(s)+3CO2(g)]+[2FeO(s)+2CO(g)]
⇒Fe2O3(s)+CO(g)→2FeO(s)+CO2(g)
Therefore, the enthalpy change for the target reaction is:
ΔH=ΔH1+ΔH3=−26.88 kJ+33.0 kJ=+6.12 kJ≈+6.2 kJ