Back to Directory
NEET CHEMISTRYMedium

The following two reactions are known: Fe2O3(s)+3CO(g)2Fe(s)+3CO2(g);ΔH=26.88 kJ\text{Fe}_2\text{O}_3(s) + 3\text{CO}(g) \rightarrow 2\text{Fe}(s) + 3\text{CO}_2(g); \Delta H = -26.88\text{ kJ} FeO(s)+CO(g)Fe(s)+CO2(g);ΔH=16.5 kJ\text{FeO}(s) + \text{CO}(g) \rightarrow \text{Fe}(s) + \text{CO}_2(g); \Delta H = -16.5\text{ kJ} The value of ΔH\Delta H for the following reaction: Fe2O3(s)+CO(g)2FeO(s)+CO2(g)\text{Fe}_2\text{O}_3(s) + \text{CO}(g) \rightarrow 2\text{FeO}(s) + \text{CO}_2(g) is:

A

43.3 kJ-43.3\text{ kJ}

B

10.3 kJ-10.3\text{ kJ}

C

+6.2 kJ+6.2\text{ kJ}

D

+10.3 kJ+10.3\text{ kJ}

Step-by-Step Solution

Let the given reactions be: (i) Fe2O3(s)+3CO(g)2Fe(s)+3CO2(g);ΔH1=26.88 kJ\text{Fe}_2\text{O}_3(s) + 3\text{CO}(g) \rightarrow 2\text{Fe}(s) + 3\text{CO}_2(g); \Delta H_1 = -26.88\text{ kJ} (ii) FeO(s)+CO(g)Fe(s)+CO2(g);ΔH2=16.5 kJ\text{FeO}(s) + \text{CO}(g) \rightarrow \text{Fe}(s) + \text{CO}_2(g); \Delta H_2 = -16.5\text{ kJ}

The target reaction is: Fe2O3(s)+CO(g)2FeO(s)+CO2(g);ΔH=?\text{Fe}_2\text{O}_3(s) + \text{CO}(g) \rightarrow 2\text{FeO}(s) + \text{CO}_2(g); \Delta H = ?

By applying Hess's Law, we can obtain the target reaction by reversing equation (ii), multiplying it by 2, and then adding it to equation (i): Reverse equation (ii) and multiply by 2: 2Fe(s)+2CO2(g)2FeO(s)+2CO(g);ΔH3=2×(+16.5 kJ)=+33.0 kJ2\text{Fe}(s) + 2\text{CO}_2(g) \rightarrow 2\text{FeO}(s) + 2\text{CO}(g); \Delta H_3 = 2 \times (+16.5\text{ kJ}) = +33.0\text{ kJ}

Now, add this to equation (i): [Fe2O3(s)+3CO(g)]+[2Fe(s)+2CO2(g)][2Fe(s)+3CO2(g)]+[2FeO(s)+2CO(g)][\text{Fe}_2\text{O}_3(s) + 3\text{CO}(g)] + [2\text{Fe}(s) + 2\text{CO}_2(g)] \rightarrow [2\text{Fe}(s) + 3\text{CO}_2(g)] + [2\text{FeO}(s) + 2\text{CO}(g)] Fe2O3(s)+CO(g)2FeO(s)+CO2(g)\Rightarrow \text{Fe}_2\text{O}_3(s) + \text{CO}(g) \rightarrow 2\text{FeO}(s) + \text{CO}_2(g)

Therefore, the enthalpy change for the target reaction is: ΔH=ΔH1+ΔH3=26.88 kJ+33.0 kJ=+6.12 kJ+6.2 kJ\Delta H = \Delta H_1 + \Delta H_3 = -26.88\text{ kJ} + 33.0\text{ kJ} = +6.12\text{ kJ} \approx +6.2\text{ kJ}

Practice Mode Available

Master this Topic on Sushrut

Join thousands of students and practice with AI-generated mock tests.

Get Started