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NEET ChemistryMedium

Find out the solubility of Ni(OH)2Ni(OH)_2 in 0.1 M NaOHNaOH. Given that the ionic product of Ni(OH)2Ni(OH)_2 is 2×10152 \times 10^{-15}

1

2×10132 \times 10^{-13} M

2

2×1082 \times 10^{-8} M

3

1×10131 \times 10^{-13} M

4

1×1081 \times 10^{8} M

Step-by-Step Solution

Ni(OH)2Ni2++2OHNi(OH)_2 \rightleftharpoons Ni^{2+} + 2OH^-. NaOHNa++OHNaOH \rightarrow Na^+ + OH^-. Total [OH]=2s+0.10.1[OH^-] = 2s + 0.1 \approx 0.1. Ionic product = [Ni2+][OH]2[Ni^{2+}][OH^-]^2. 2×1015=s(0.1)22 \times 10^{-15} = s(0.1)^2. s=2×1013s = 2 \times 10^{-13}. Solubility of Ni(OH)2=2×1013Ni(OH)_2 = 2 \times 10^{-13} M.

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