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NEET CHEMISTRYMedium

The most preferred structure among the following with the lowest energy for SO3SO_{3} is:

A

A structure in which the sulphur atom is attached to three oxygen atoms by three double bonds.

B

A structure in which the sulphur atom is attached to one oxygen atom by a double bond and two oxygen atoms by single bonds.

C

A structure in which the sulphur atom is attached to two oxygen atoms by double bonds and one oxygen atom by a single bond.

D

A structure in which the sulphur atom is attached to three oxygen atoms by single bonds.

Step-by-Step Solution

According to the principles of chemical bonding found in the sources, the preference for a particular Lewis structure is determined by formal charges . The sources state that 'Generally the lowest energy structure is the one with the smallest formal charges on the atoms' .

  1. Sulphur's Valence: Sulphur belongs to the third period and can expand its octet to accommodate more than eight valence electrons because it has 3d orbitals available for bonding .
  2. Formal Charge Calculation: In a structure where Sulphur forms three double bonds with three Oxygen atoms:
  • Formal Charge on S: 66 (valence) 0- 0 (lone pairs) 12(12)- \frac{1}{2}(12) (bonding electrons) =0= 0.
  • Formal Charge on each O: 66 (valence) 4- 4 (lone pairs) 12(4)- \frac{1}{2}(4) (bonding electrons) =0= 0. Since all atoms in this structure have a formal charge of zero, it is the most stable, lowest energy, and thus the most preferred structure compared to those where Sulphur maintains an octet but carries a high positive formal charge (like +2) .
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