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NEET CHEMISTRYMedium

The decrease in size from left to right in the actinoid series is greater and more gradual than that in the lanthanoid series due to:

A

4f4f orbitals are penultimate

B

4f4f orbitals have a greater shielding effect

C

5f5f orbitals have a poor shielding effect

D

5f5f orbitals have a greater shielding effect

Step-by-Step Solution

Similar to the lanthanoids, actinoids exhibit a gradual decrease in the size of their atoms or M3+M^{3+} ions across the series, a phenomenon known as actinoid contraction. However, the contraction is greater from element to element in the actinoid series compared to the lanthanoid series. This occurs because the 5f5f electrons provide poorer shielding from the increasing nuclear charge than the 4f4f electrons . As a result, the outer electrons are pulled more strongly towards the nucleus, leading to a greater decrease in atomic and ionic sizes.

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