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NEET CHEMISTRYHard

Jahn-Teller effect is not observed in high spin complexes of:

A

d^7

B

d^8

C

d^4

D

d^9

Step-by-Step Solution

The Jahn-Teller effect occurs in non-linear molecules where the electronic configuration creates degeneracy (unequal occupation of degenerate orbitals), leading to geometric distortion to lower symmetry and energy. It is observed when the t2gt_{2g} or ege_g orbitals are unsymmetrically filled.

  1. Analyze High Spin Configurations (Octahedral Field):
  • d4d^4: Configuration is t2g3eg1t_{2g}^3 e_g^1. The ege_g level is unsymmetrically filled (1 electron in 2 orbitals). Shows strong Jahn-Teller distortion .
  • d7d^7: Configuration is t2g5eg2t_{2g}^5 e_g^2. The t2gt_{2g} level is unsymmetrically filled (5 electrons in 3 orbitals). Shows Jahn-Teller distortion.
  • d9d^9: Configuration is t2g6eg3t_{2g}^6 e_g^3. The ege_g level is unsymmetrically filled (3 electrons in 2 orbitals). Shows strong Jahn-Teller distortion .
  • d8d^8: Configuration is t2g6eg2t_{2g}^6 e_g^2. The lower t2gt_{2g} set is completely filled (symmetric), and the upper ege_g set is exactly half-filled (symmetric). Because both sets of orbitals are symmetrically occupied, there is no electronic degeneracy .
  1. Conclusion: The d8d^8 high spin configuration does not exhibit the Jahn-Teller effect.
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