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NEET CHEMISTRYMedium

The intermediate compound 'X' in the following chemical reaction is: TolueneCrO2Cl2/CS2XH3O+Benzaldehyde\text{Toluene} \xrightarrow{CrO_2Cl_2/CS_2} X \xrightarrow{H_3O^+} \text{Benzaldehyde}

A

C6H5CH2ClC_6H_5-CH_2Cl

B

C6H5CHCl2C_6H_5-CHCl_2

C

C6H5CH(OH)2C_6H_5-CH(OH)_2

D

C6H5CH(OCrOHCl2)2C_6H_5-CH(OCrOHCl_2)_2

Step-by-Step Solution

The given reaction is the Etard reaction. In this reaction, chromyl chloride (CrO2Cl2CrO_2Cl_2) is used as an oxidizing agent in a non-polar solvent like CS2CS_2. It oxidizes the methyl group of toluene to form a brown-coloured chromium complex as an intermediate. This intermediate complex, upon subsequent acid hydrolysis (H3O+H_3O^+), yields benzaldehyde. The structure of the intermediate chromium complex 'X' is C6H5CH(OCrOHCl2)2C_6H_5-CH(OCrOHCl_2)_2.

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