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NEET CHEMISTRYMedium

Bond dissociation enthalpy of H2\text{H}_2, Cl2\text{Cl}_2, and HCl\text{HCl} are 434434, 242242, and 431 kJ mol1431 \text{ kJ mol}^{-1} respectively. Enthalpy of formation of HCl\text{HCl} is:

A

93 kJ mol193 \text{ kJ mol}^{-1}

B

245 kJ mol1-245 \text{ kJ mol}^{-1}

C

93 kJ mol1-93 \text{ kJ mol}^{-1}

D

245 kJ mol1245 \text{ kJ mol}^{-1}

Step-by-Step Solution

The chemical equation for the formation of HCl(g)\text{HCl(g)} from its constituent elements in their standard states is: 12H2(g)+12Cl2(g)HCl(g)\frac{1}{2}\text{H}_2\text{(g)} + \frac{1}{2}\text{Cl}_2\text{(g)} \rightarrow \text{HCl(g)}

The standard enthalpy of formation (ΔfH\Delta_f H^{\circ}) can be calculated from the given bond dissociation enthalpies (ΔbondH\Delta_{\text{bond}} H^{\circ}) using the relation: ΔfH=ΔbondH(reactants)ΔbondH(products)\Delta_f H^{\circ} = \sum \Delta_{\text{bond}} H^{\circ}(\text{reactants}) - \sum \Delta_{\text{bond}} H^{\circ}(\text{products})

Substituting the given values into the equation: ΔfH(HCl)=[12ΔbondH(H2)+12ΔbondH(Cl2)][ΔbondH(HCl)]\Delta_f H^{\circ}(\text{HCl}) = \left[ \frac{1}{2} \Delta_{\text{bond}} H^{\circ}(\text{H}_2) + \frac{1}{2} \Delta_{\text{bond}} H^{\circ}(\text{Cl}_2) \right] - \left[ \Delta_{\text{bond}} H^{\circ}(\text{HCl}) \right] ΔfH(HCl)=[12(434)+12(242)]431\Delta_f H^{\circ}(\text{HCl}) = \left[ \frac{1}{2}(434) + \frac{1}{2}(242) \right] - 431 ΔfH(HCl)=(217+121)431\Delta_f H^{\circ}(\text{HCl}) = (217 + 121) - 431 ΔfH(HCl)=338431=93 kJ mol1\Delta_f H^{\circ}(\text{HCl}) = 338 - 431 = -93 \text{ kJ mol}^{-1}

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