The chemical equation for the formation of HCl(g) from its constituent elements in their standard states is:
21H2(g)+21Cl2(g)→HCl(g)
The standard enthalpy of formation (ΔfH∘) can be calculated from the given bond dissociation enthalpies (ΔbondH∘) using the relation:
ΔfH∘=∑ΔbondH∘(reactants)−∑ΔbondH∘(products)
Substituting the given values into the equation:
ΔfH∘(HCl)=[21ΔbondH∘(H2)+21ΔbondH∘(Cl2)]−[ΔbondH∘(HCl)]
ΔfH∘(HCl)=[21(434)+21(242)]−431
ΔfH∘(HCl)=(217+121)−431
ΔfH∘(HCl)=338−431=−93 kJ mol−1