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For a reaction ABA \rightarrow B, enthalpy of reaction is 4.2 kJ mol1-4.2 \text{ kJ mol}^{-1} and enthalpy of activation is 9.6 kJ mol19.6 \text{ kJ mol}^{-1}. The correct potential energy profile for the reaction is:

A

Option 1

B

Option 2

C

Option 3

D

Option 4

Step-by-Step Solution

The given reaction is ABA \rightarrow B. Enthalpy of reaction, ΔH=4.2 kJ mol1\Delta H = -4.2 \text{ kJ mol}^{-1}. The negative sign indicates that the reaction is exothermic. Therefore, the potential energy of the product (B) will be lower than the potential energy of the reactant (A) by 4.2 kJ mol14.2 \text{ kJ mol}^{-1}. Activation energy, Ea=9.6 kJ mol1E_a = 9.6 \text{ kJ mol}^{-1}. This means the energy barrier (peak of the curve) is 9.6 kJ mol19.6 \text{ kJ mol}^{-1} above the energy of the reactant (A). The correct potential energy profile will show the reactant A at a certain energy level, a peak 9.6 kJ mol19.6 \text{ kJ mol}^{-1} above A, and the product B at an energy level 4.2 kJ mol14.2 \text{ kJ mol}^{-1} below A.

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