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NEET CHEMISTRYMedium

The hybridisation of Ni in the complex [Ni(CN)4]2[Ni(CN)_4]^{2-} is: (Atomic number of Ni = 28)

A

dsp2dsp^2

B

sp3sp^3

C

sp3d2sp^3d^2

D

d2sp3d^2sp^3

Step-by-Step Solution

In the complex [Ni(CN)4]2[Ni(CN)_4]^{2-}, the central metal ion is Ni in the +2 oxidation state. The ground state electronic configuration of Ni is [Ar]3d84s2[Ar] 3d^8 4s^2, so Ni2+Ni^{2+} has a 3d83d^8 configuration. Because CNCN^- is a strong field ligand, it causes the pairing of the two unpaired 3d3d electrons. This leaves one 3d3d orbital vacant. This empty inner 3d3d orbital, along with one 4s4s orbital and two 4p4p orbitals, undergoes dsp2dsp^2 hybridization to form four equivalent hybrid orbitals directed towards the corners of a square. These empty hybrid orbitals accept electron pairs from four cyanide ligands. Thus, the complex has a square planar geometry and dsp2dsp^2 hybridization.

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