The hybridisation of Ni in the complex is: (Atomic number of Ni = 28)
In the complex , the central metal ion is Ni in the +2 oxidation state. The ground state electronic configuration of Ni is , so has a configuration. Because is a strong field ligand, it causes the pairing of the two unpaired electrons. This leaves one orbital vacant. This empty inner orbital, along with one orbital and two orbitals, undergoes hybridization to form four equivalent hybrid orbitals directed towards the corners of a square. These empty hybrid orbitals accept electron pairs from four cyanide ligands. Thus, the complex has a square planar geometry and hybridization.
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