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Match the statements given in List-I with the corresponding element given in List-II:

List-I (Characteristics) (a) Element that exhibits +3 oxidation state only. (b) An element that exhibits a greater number of oxidation states. (c) Element which is a reducing agent in its +2 oxidation state. (d) An element that is not considered as a transition element.

List-II (Elements) (i) Mn (ii) Zn (iii) Sc (iv) Cr

Choose the correct answer from the options given below:

A

(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)

B

(a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)

C

(a)-(ii), (b)-(iv), (c)-(iii), (d)-(i)

D

(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)

Step-by-Step Solution

Let us match the characteristics with the respective elements: (a) Scandium (Sc) exhibits only a +3 oxidation state because losing its three valence electrons gives it a highly stable noble gas configuration . (b) Manganese (Mn) gives the greatest number of oxidation states (from +2 to +7) due to the involvement of maximum unpaired electrons in its 3d3d and 4s4s orbitals . (c) Chromium (Cr) acts as a strong reducing agent in its +2 oxidation state (Cr2+Cr^{2+}) because its oxidation to Cr3+Cr^{3+} changes its configuration from d4d^4 to a highly stable half-filled t2g3t_{2g}^3 configuration . (d) Zinc (Zn) is not considered a transition metal because it has a completely filled d10d^{10} electronic configuration in its ground state as well as in its common oxidation state (+2) . Therefore, the correct match is (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii).

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