For the gas phase reaction, PCl5(g)⇌PCl3(g)+Cl2(g), which of the following conditions is correct?
A
ΔH=0 and ΔS<0
B
ΔH>0 and ΔS>0
C
ΔH<0 and ΔS<0
D
ΔH>0 and ΔS<0
Step-by-Step Solution
For the given decomposition reaction:
PCl5(g)⇌PCl3(g)+Cl2(g)
Enthalpy change (ΔH): Decomposition reactions typically involve the breaking of bonds, which requires an input of energy. Therefore, the reaction is endothermic, meaning ΔH>0 (specifically, ΔrH∘=124.0 kJ mol−1).
Entropy change (ΔS): In this reaction, 1 mole of a gaseous reactant decomposes to form 2 moles of gaseous products (Δng=1+1−1=+1). Since the number of gaseous particles increases, the randomness or disorder of the system also increases. Therefore, ΔS>0.
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