The temperature dependence of the rate constant () of a chemical reaction is written in terms of the Arrhenius equation, . The activation energy () of the reaction can be calculated by plotting:
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According to the Arrhenius equation, the rate constant is given by . Taking the natural logarithm on both sides yields . Converting this to base-10 logarithm gives . This is the equation of a straight line (), where and . Therefore, a plot of versus gives a straight line with a slope of . The activation energy () can be calculated from the value of this slope.
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