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NEET CHEMISTRYEasy

The temperature dependence of the rate constant (kk) of a chemical reaction is written in terms of the Arrhenius equation, k=AeE/RTk = A e^{-E^*/RT}. The activation energy (EE^*) of the reaction can be calculated by plotting:

A

kk vs TT

B

kk vs 1logT\frac{1}{\log T}

C

logk\log k vs 1T\frac{1}{T}

D

logk\log k vs 1logT\frac{1}{\log T}

Step-by-Step Solution

According to the Arrhenius equation, the rate constant kk is given by k=AeE/RTk = A e^{-E^*/RT}. Taking the natural logarithm on both sides yields lnk=lnAERT\ln k = \ln A - \frac{E^*}{RT}. Converting this to base-10 logarithm gives logk=logAE2.303RT\log k = \log A - \frac{E^*}{2.303RT}. This is the equation of a straight line (y=mx+cy = mx + c), where y=logky = \log k and x=1Tx = \frac{1}{T}. Therefore, a plot of logk\log k versus 1T\frac{1}{T} gives a straight line with a slope of E2.303R-\frac{E^*}{2.303R}. The activation energy (EE^*) can be calculated from the value of this slope.

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