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NEET CHEMISTRYMedium

When neutral or faintly alkaline KMnO4KMnO_4 is treated with potassium iodide, iodide ion is converted into 'X'. 'X' is:

A

I2I_2

B

IO4IO_4^-

C

IO3IO_3^-

D

IOIO^-

Step-by-Step Solution

Potassium permanganate (KMnO4KMnO_4) acts as a strong oxidising agent. Its reaction product with iodide depends on the pH of the medium:

  1. In acidic medium: Iodide (II^-) is oxidised to iodine (I2I_2).
  2. In neutral or faintly alkaline solution: Iodide (II^-) is oxidised to iodate (IO3IO_3^-). The manganese is reduced from +7 (MnO4MnO_4^-) to +4 (MnO2MnO_2).

The specific reaction equation provided in the NCERT text is: 2MnO4+H2O+I2MnO2+2OH+IO32MnO_4^- + H_2O + I^- \rightarrow 2MnO_2 + 2OH^- + IO_3^-

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