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NEET CHEMISTRYMedium

Which of the following is not a correct statement?

A

The electron-deficient molecules can act as Lewis acids

B

The canonical structures have no real existence

C

Every AB5\text{AB}_5 molecule does, in fact, have square pyramid structure

D

Multiple bonds are always shorter than corresponding single bonds

Step-by-Step Solution

According to VSEPR theory, a molecule of the type AB5\text{AB}_5 (where the central atom 'A' has 5 bond pairs and 0 lone pairs) has a trigonal bipyramidal geometry (e.g., PCl5\text{PCl}_5) . A square pyramidal geometry is observed in molecules of the type AB5E\text{AB}_5\text{E}, where the central atom has 5 bond pairs and 1 lone pair (e.g., BrF5\text{BrF}_5) . Therefore, the statement that every AB5\text{AB}_5 molecule has a square pyramidal structure is incorrect. The other statements are true: electron-deficient species act as Lewis acids , canonical (resonance) structures are hypothetical and have no real existence , and multiple bonds (double/triple) are shorter than their corresponding single bonds .

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