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NEET CHEMISTRYMedium

Given that the equilibrium constant for the reaction 2SO2(g)+O2(g)2SO3(g)2\text{SO}_2(g) + \text{O}_2(g) \rightleftharpoons 2\text{SO}_3(g) has a value of 278278 at a particular temperature, the value of the equilibrium constant for the following reaction at the same temperature will be: SO3(g)SO2(g)+12O2(g)\text{SO}_3(g) \rightleftharpoons \text{SO}_2(g) + \frac{1}{2} \text{O}_2(g)

A

3.6×1033.6 \times 10^{-3}

B

6.0×1026.0 \times 10^{-2}

C

1.3×1051.3 \times 10^{-5}

D

1.8×1031.8 \times 10^{-3}

Step-by-Step Solution

Let the given reaction be: (i) 2SO2(g)+O2(g)2SO3(g)2\text{SO}_2(g) + \text{O}_2(g) \rightleftharpoons 2\text{SO}_3(g); K1=278K_1 = 278

The target reaction is: (ii) SO3(g)SO2(g)+12O2(g)\text{SO}_3(g) \rightleftharpoons \text{SO}_2(g) + \frac{1}{2}\text{O}_2(g)

Reaction (ii) is obtained by reversing reaction (i) and dividing it by 22 (or multiplying by 12\frac{1}{2}). When a reaction is reversed, its equilibrium constant becomes the inverse of the original . When a reaction is multiplied by a factor nn, the new equilibrium constant is the original equilibrium constant raised to the power nn . Therefore, the equilibrium constant K2K_2 for reaction (ii) will be: K2=(1K1)12=1K1K_2 = \left(\frac{1}{K_1}\right)^{\frac{1}{2}} = \frac{1}{\sqrt{K_1}} K2=1278=116.670.05996.0×102K_2 = \frac{1}{\sqrt{278}} = \frac{1}{16.67} \approx 0.0599 \approx 6.0 \times 10^{-2}.

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